When gas particles collide with a surface

Butadiene undergoes a reaction at a certain temperature in the gas phase as follows: 2c4h6(g) --> c8h12(g) the following data were collected for this reaction: time (min) [c4h6] (m) 0 0.36 15 0.30 30 0.25 48 0.19 75 0. determine the order of the reaction and the rate constant. 1st order and k = 4.3x10 -4 s-1 1st order and k = 2.3x10-4 s-1 2nd order and k = 4.3x10-4 s-1 2nd order and k = 2.3x10-4 s-1 zero and k = 4.3x10-4 s-1

Can someone me with questions 12 and 13 plz.

The characteristics of two different types of reactions are shown below: reaction a: electrons are gained by the atoms of an element. reaction b: protons are lost by the atom of an element. which statement is true about the atoms of the elements that participate in the two reactions? their identity changes in both reaction a and reaction b. their identity changes in reaction a but not in reaction b. their identity changes in reaction b but not in reaction a. their identity remains the same in both reaction a and reaction b.