determine the frequency and wavelength (in nm) of the light emitted when the e- fell from n=4 and n=2

Frequency = 6.16 ×10¹⁴ Hz

λ = 4.87×10² nm

Explanation:

In case of hydrogen atom energy associated with nth state is,

En =  -13.6/n²

For n = 2

E₂ = -13.6 / 2²

E₂ = -13.6/4

E₂ = -3.4 ev

Kinetic energy of electron = -E₂ = 3.4 ev

For n = 4

E₄ = -13.6 / 4²

E₄ = -13.6/16

E₄ = -0.85 ev

Kinetic energy of electron = -E₄ = 0.85 ev

Wavelength of radiation emitted:

E = hc/λ = E₄ - E₂

hc/λ = E₄ - E₂

by putting values,

6.63×10⁻³⁴Js × 3×10⁸m/s / λ = -0.85ev   - (-3.4ev )

6.63×10⁻³⁴ Js× 3×10⁸m/s / λ = 2.55 ev

λ = 6.63×10⁻³⁴ Js× 3×10⁸m/s  /2.55ev

λ = 6.63×10⁻³⁴ Js× 3×10⁸m/s  /2.55× 1.6×10⁻¹⁹ J

λ = 19.89 ×10⁻²⁶ Jm / 2.55× 1.6×10⁻¹⁹ J

λ = 19.89 ×10⁻²⁶ Jm / 4.08×10⁻¹⁹ J

λ = 4.87×10⁻⁷ m

m to nm:

4.87×10⁻⁷ m ×10⁹nm/1 m

4.87×10² nm

Frequency:

Frequency = speed of electron / wavelength

by putting values,

Frequency = 3×10⁸m/s /4.87×10⁻⁷ m

Frequency = 6.16 ×10¹⁴ s⁻¹

s⁻¹ = Hz

Frequency = 6.16 ×10¹⁴ Hz

"standard molar enthalpy:

h2o ( liquid water ) : - 285.8 kj/mole

h2o ( water vapor ) : - 241.8 kj / mole.

δhrxn = - 241. 8 - ( - 285.8 )= -241.8 + 285.8 = 44.0

answer: 44.0 kj"