Starting at atmospheric pressure, by how much must the pressure change in order to lower the boiling point of water by 1° C? You may assume that these changes are both small, so you only need to compute first derivatives. Remember that, under most conditions, the volume (per molecule) of liquid water is small compared to that of water vapor. Remember: Atmospheric pressure = 101300 Pa Boiling point at atmospheric pressure = 373.15 K Latent heat (LB) of boiling water = 2.256 × 106 J/kg Molecular weight (mw) of water = 0.018 kg/mol

ΔP = -3556.36 Pa

Explanation:

Atmospheric pressure, P = 101300 Pa

Latent heat of boiling water,

Boiling point at atmospheric pressure, T = 373.15 K

ΔT = 1 K

The change in volume as the water boils to vapor will be

Since the volume of vapor () is far greater than the volume of liquid ()

Using the ideal gas equation:

R = 8.314 J/mol-K

ΔV = 0.0306 m³

Molecular weight of water, MW = 0.018 kg/mol

Using the Clausius - Clapeyron equation:

ΔP = -3556.36 Pa

But the pressure change is said to lower the boiling point of water, only a negative pressure change will lower the boiling point.

ΔP = 3556.36 Pa

according to the u.s. department of agriculture, the label of "certified organic" comes with a set of highly regulated standards for environmental stewardship and resource conservation. some of these include maintenance and improvement of soil quality, prevention of ground and surface water contamination, greenhouse gas regulation, encouragement of biodiversity and conservation of water and energy (see references 1). organic practices integrate natural methods such as mulching, plant diversity, native and adapted plants, crop rotation and the introduction of beneficial insects to control pests without synthetic pesticides.

environmental implications of pesticides

synthetic pesticides ensure high crop yields. while effective in achieving this goal, pesticides contaminate soil, air, ground and surface water, as well as the plants and animals that come into contact with these contaminated sources. freshwater and marine organisms are particularly susceptible to pesticides through agricultural runoff. pesticides also reduce soil fertility (necessitating the use of synthetic fertilizers) and can travel far from the original source, contaminating water and air hundreds of miles from the location of application (see references 2).

health implications of organics

although a subject of particular debate, many recent findings show that organic food is healthier than conventionally grown food. according to the usda, an extensive european union-funded study found that organically grown foods contain more beneficial compounds, such as the vitamins and antioxidants needed to combat many diseases (see references 5). organic milk, meat and eggs are regulated to ensure they are free of hormones administered to conventional livestock and poultry.

health implications of pesticides

pesticides affect human health in three ways: through skin contact, inhalation and ingestion. acute and long-term exposure to pesticides can cause serious health problems for farmers who apply them. the majority of other people are affected by drinking contaminated water and eating contaminated marine life (see references 3). pesticides have been linked to neurological disorders, endocrine and reproductive disorders, immune system deficiencies and cancer. according to the world health organization, acute pesticide poisoning (app) is responsible for significant annual mortality, especially in developing nations (see references 4).

other important considerations

not every small farm or business owner can afford the costly certification process required to be considered "certified organic," even if the farm is not using chemicals. "transitional" farms include those that once used chemicals and are now transitioning to organic-only production. in addition, though organic farming methods offer obvious environmental benefit, an organic apple shipped from around the world creates a different set of environmental problems. locally grown food (particularly locally grown, organic food) is key in sustainable food production.