Will give big prizes !! Can you guys explain why when mixing warm water with baking soda, it floats an object such as a grape, and when mixing cold water with baking soda, it doesn't float objects such as grapes? Does it have anything to do with particles?

Will you chech and finish these for me, because i am stumped with them.

Classify the following soils according to the uscs classification system. provide appropriate uscs designations. a) this sample of well-graded gravel with sand was obtained from a large earthen dam in vancouver, canada. the sample has 73% fine to coarse sub-angular gravel, 25% fine to coarse sub-angular sand and 2% fines. the maximum size of the particles is 75 mm. the coefficient of curvature is 2.7, while the uniformity coefficient is 12.4. b) this dark brown and wet soil with a “strong organic odor” has 100% passing the no. 200 sieve. the liquid limit of the material is 32% when not dried and is 21% when oven-dried. the plastic index is 21% when not dried. c) this sand has 61% predominantly fine sand, 23% silty fines, and 16% fine sub-rounded gravel size. the maximum size is 20 mm. the liquid limit is 33% and the plastic limit is 27%. d) this soil has 74% fine to coarse sub-angular reddish sand and 26% organic and silty dark brown fines. the liquid limit is 37% when not dried and is 26% when oven dried. the plastic index is 6% when not dried.

The particle in a two-dimensional well is a useful model for the motion of electrons around the indole ring (3), the conjugated cycle found in the side chain of tryptophan. we may regard indole as a rectangle with sides of length 280 pm and 450 pm, with 10 electrons in the conjugated p system. as in case study 9.1, we assume that in the ground state of the molecule each quantized level is occupied by two electrons. (a) calculate the energy of an electron in the highest occupied level. (b) calculate the frequency of radiation that can induce a transition between the highest occupied and lowest unoccupied levels. 9.27 electrons around the porphine ring (4), the conjugated macrocycle that forms the structural basis of the heme group and the chlorophylls. we may treat the group as a circular ring of radius 440 pm, with 20 electrons in the conjugated system moving along the perimeter of the ring. as in exercise 9.26, assume that in the ground state of the molecule quantized each level is occupied by two electrons. (a) calculate the energy and angular momentum of an electron in the highest occupied level. (b) calculate the frequency of radiation that can induce a transition between the highest occupied and lowest unoccupied levels.