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The particle in a two-dimensional well is a useful model for the motion of electrons around the indole ring (3), the conjugated cycle found in the side chain of tryptophan. we may regard indole as a rectangle with sides of length 280 pm and 450 pm, with 10 electrons in the conjugated p system. as in case study 9.1, we assume that in the ground state of the molecule each quantized level is occupied by two electrons. (a) calculate the energy of an electron in the highest occupied level. (b) calculate the frequency of radiation that can induce a transition between the highest occupied and lowest unoccupied levels. 9.27 electrons around the porphine ring (4), the conjugated macrocycle that forms the structural basis of the heme group and the chlorophylls. we may treat the group as a circular ring of radius 440 pm, with 20 electrons in the conjugated system moving along the perimeter of the ring. as in exercise 9.26, assume that in the ground state of the molecule quantized each level is occupied by two electrons. (a) calculate the energy and angular momentum of an electron in the highest occupied level. (b) calculate the frequency of radiation that can induce a transition between the highest occupied and lowest unoccupied levels.

Using a wheel and axle, a farmer is trying to lift a bucket of water from the bottom of a well. the larger wheel has a radius of 40 cm compared to the axle that has a radius of 10 cm. if a bucket of water is 50 n, then how much effort is required to raise it? 12.5 n 200 n 2 n 500 n

Aleaky 10-kg bucket is lifted from the ground to a height of 15 m at a constant speed with a rope that weighs 0.7 kg/m. initially the bucket contains 45 kg of water, but the water leaks at a constant rate and finishes draining just as the bucket reaches the 15-m level. find the work done. (use 9.8 m/s2 for g.) show how to approximate the required work by a riemann sum. (let x be the height in meters above the ground. enter xi* as xi.) lim n → ∞ n (9.8)(45−3 xi) i = 1 δx express the work as an integral. 0 dx evaluate the integral. (round your answer to the nearest integer.) j