Someone please help with these 2

Glass is transparent to visibile light under normal conditions; however, at extremely high intensities, glass will absorb most of the light incident upon it. this works through a process known as multiphoton absorption. in this process, several photons are absorbed at the same time. if very intense light whose photons carry 2ev of energy is shined onto a material with a band gap of 4ev, that light can be absorbed through two-photon absorption, because two photons have the right amount of energy to bridge the band gap. what is the minimum number of photons of 800-nm light that are needed to equal or exceed the band gap of fused silica glass

Clothing made of several thin layers of fabric with trapped air in between, often called ski clothing, is commonly used in cold climates because it is light, fashionable, and a very effective thermal insulator. so it is no surprise that such clothing has largely replaced thickand heavy old-fashioned coats. (a) consider a jacket made of five layers of 0.1-mm-thick synthetic fabric (k = 0.13 w/m·°c) with 1.5-mm-thick air space (k = 0.026 w/m·°c) between the layers. assuming the inner surface temperature of the jacket to be 28°c and the surface area to be 1.25 m2, determine the rate of heat loss through the jacket when the temperature of the outdoors is 0°c and the heat transfer coefficient at the outer surface is 25 w/m2·°c. (b) what would your response be if the jacket is made of a single layer of 0.5-mm-thick synthetic fabric? what should be the thickness of a wool fabric (k = 0.035 w/m·°c) if the person is to achieve the same level of thermal comfort wearing a thick wool coat instead of a five-layer ski jacket?

Nitrogen (n2) undergoes an internally reversible process from 6 bar, 247°c during which pν1.2 = constant. the initial volume is 0.1 m3 and the work for the process is 121.14 kj. assuming ideal gas behavior, and neglecting kinetic and potential energy effects, determine heat transfer, in kj, and the entropy change, in kj/s. show the process on a t-s diagram.