A rate law for which the units of rate are equal to the units of the rate constant is the zero order kinetics? A. True
B. False​

In the derivation of rrkm theory, a factor of 1/2 is introduced when equalizing the rates of formation and decomposition of activated complex as keal-hr) = ko this is clearly against the assumption of transition state theory that states all the activated complex in the transition state iss going to the product. find the reason why this factor is introduced here.

The particle in a two-dimensional well is a useful model for the motion of electrons around the indole ring (3), the conjugated cycle found in the side chain of tryptophan. we may regard indole as a rectangle with sides of length 280 pm and 450 pm, with 10 electrons in the conjugated p system. as in case study 9.1, we assume that in the ground state of the molecule each quantized level is occupied by two electrons. (a) calculate the energy of an electron in the highest occupied level. (b) calculate the frequency of radiation that can induce a transition between the highest occupied and lowest unoccupied levels. 9.27 electrons around the porphine ring (4), the conjugated macrocycle that forms the structural basis of the heme group and the chlorophylls. we may treat the group as a circular ring of radius 440 pm, with 20 electrons in the conjugated system moving along the perimeter of the ring. as in exercise 9.26, assume that in the ground state of the molecule quantized each level is occupied by two electrons. (a) calculate the energy and angular momentum of an electron in the highest occupied level. (b) calculate the frequency of radiation that can induce a transition between the highest occupied and lowest unoccupied levels.

As part of an industrial process, air as an ideal gas at 10 bar, 400k expands at steady state through a valve to a pressure of 4 bar. the mass flow rate of air is 0.5 kg/s. the air then passes through a heat exchanger where it is cooled to a temperature of 295k with negligible change in pressure. the valve can be modeled as a throttling process, and kinetic and potential energy effects can be neglected. (a) for a control volume enclosing the valve and heat exchanger and enough of the local surroundings that the heat transfer occurs at the ambient temperature of 295 k, determine the rate of entropy production, in kw/k. (b) if the expansion valve were replaced by an adiabatic turbine operating isentropically, what would be the entropy production? compare the results of parts (a) and (b) and discuss.