I need some help please!!

In the derivation of rrkm theory, a factor of 1/2 is introduced when equalizing the rates of formation and decomposition of activated complex as keal-hr) = ko this is clearly against the assumption of transition state theory that states all the activated complex in the transition state iss going to the product. find the reason why this factor is introduced here.

Astudent pushes on a 20.0 kg box with a force of 50 n at an angle of 30° below the horizontal. the box accelerates at a rate of 0.5 m/s2 across a horizontal floor. what is the value of the normal force on the box? 200 n 243 n 156 n 225 n

The temperature in gavin's oven is a sinusoidal function of time. gavin sets his oven so that it has a maximum temperature of 280°f and a minimum temperature of 240°. once the temperature hits 280°, it takes 20 minutes before it is 280° again. gavin's cake needs to be in the oven for 30 minutes at temperatures at or above 270°. he puts the cake into the oven when it is at 260° and rising. how long will gavin need to leave the cake in the oven? (round your answer to the nearest minute.)