Why can't the efficiency of a heat engine be 100%?

Agas is contained in a vertical, frictionless piston–cylinder device. the piston has a mass of 3.2 kg and a cross-sectional area of 35 cm2. a compressed spring above the piston exerts a force of 190 n on the piston. if the atmospheric pressure is 95 kpa, determine the pressure inside the cylinder.

A248-g piece of copper is dropped into 390 ml of water at 22.6 °c. the final temperature of the water was measured as 39.9 °c. calculate the initial temperature of the piece of copper. assume that all heat transfer occurs between the copper and the water. remember, the density of water is 1.0 g/m

What’s #16 asking me and how do i solve it?