A body in equilibrium will: (1 Remain 2 Move at a constant

The particle in a two-dimensional well is a useful model for the motion of electrons around the indole ring (3), the conjugated cycle found in the side chain of tryptophan. we may regard indole as a rectangle with sides of length 280 pm and 450 pm, with 10 electrons in the conjugated p system. as in case study 9.1, we assume that in the ground state of the molecule each quantized level is occupied by two electrons. (a) calculate the energy of an electron in the highest occupied level. (b) calculate the frequency of radiation that can induce a transition between the highest occupied and lowest unoccupied levels. 9.27 electrons around the porphine ring (4), the conjugated macrocycle that forms the structural basis of the heme group and the chlorophylls. we may treat the group as a circular ring of radius 440 pm, with 20 electrons in the conjugated system moving along the perimeter of the ring. as in exercise 9.26, assume that in the ground state of the molecule quantized each level is occupied by two electrons. (a) calculate the energy and angular momentum of an electron in the highest occupied level. (b) calculate the frequency of radiation that can induce a transition between the highest occupied and lowest unoccupied levels.

The number of passengers who arrive at the platform of a subway station for the 10 am train is a random variable with a mean of 120 and a variance of 16. find the lower bound of the probability that there will be between 100 and 140 passengers (round off to second decimal place).

Arigid tank is divided into two equal parts by a partition. one part of the tank contains 3 kg of compressed liquid water at 400 kpa and 60°c while the other part is evacuated. the partition is now removed, and the water expands to fill the entire tank. determine the entropy change of water during this process, if the final pressure in the tank is 40 kpa. use steam tables.