Out of these multiple choice, what’s the correct answer?

Glass is transparent to visibile light under normal conditions; however, at extremely high intensities, glass will absorb most of the light incident upon it. this works through a process known as multiphoton absorption. in this process, several photons are absorbed at the same time. if very intense light whose photons carry 2ev of energy is shined onto a material with a band gap of 4ev, that light can be absorbed through two-photon absorption, because two photons have the right amount of energy to bridge the band gap. what is the minimum number of photons of 800-nm light that are needed to equal or exceed the band gap of fused silica glass

Ms. hidalgo opens the door to her classroom. her classroom is 60 degrees and the air outside is 80. predict what will happen using your knowledge of how heat flows.

An insulated 40 ft^3 rigid tank contains air at 50 psia and 120°f. a valve connected to the tank is now opened, and air is allowed to escape until the pressure inside drops to 25 psia. the air temperature during this process is kept constant by an electric resistance heater placed in the tank. determine the electrical work done during this process.