The "Fundamental Relation of Thermodynamics" says that in equilibrium: where T is temperature, S is entropy, U is internal energy, p is pressure, and V is volume. This describes how, in equilibrium, S depends on changes in U and V. Here are other derivatives to evaluate, always assuming equilibrium so you can use the Fundamental Relation. The answers should be simple formulas expressed in terms of the variables S, T, U, V, and p.

  1.the balanced   chemical equation is as below

cu +   2 ag(no)₃ → cu(no₃)₂   +2 ag

2.the   much silver   produced   is   50.9 g

step 1: find the   moles of cu

moles =   mass÷   molar mass

  from periodic table the molar mass of cu = 63.5 g/mol

moles is therefore = 15.00 g÷ 63.5 g/mol = 0.236   moles

step 2: use the mole ratio to determine the   moles of ag

from equation above   cu: ag   is 1: 2

therefore the moles of ag   =0.236   moles   x 2/1 =0.472   moles

step 3: find the mass   of ag

mass = moles x molar mass

from periodic table   the molar mass of ag =107.87 g/mol

mass   = 0.472   moles x 107.87 g/mol = 50.9 g

3.   the   much   silver   collected worth is   1.797 oz

  convert   50.9 g   to oz

that is   1 gram = 0.0353 oz

          50.9 grams =?   oz

by cross multiplication

={(50.9 grams x 0.0353 oz) / 1   gram}   =1.797 oz

the motion of a pendulum is a classic example of mechanical energy conservation. a pendulum consists of a mass (known as a bob ) attached by a string to a pivot point. as the pendulum moves it sweeps out a circular arc, moving back and forth in a periodic fashion.