The reaction converting glycerol to glycerol-3-phosphate is energetically unfavorable by 9.2 kJkJ. The reaction of ATP with water to yield ADP, hydrogen phosphate ion, and hydrogen ion is energetically favorable by 30.5 kJkJ. These reactions are coupled so that the overall process is energetically favorable. What is ΔGΔGDelta G for the overall process?

As part of an industrial process, air as an ideal gas at 10 bar, 400k expands at steady state through a valve to a pressure of 4 bar. the mass flow rate of air is 0.5 kg/s. the air then passes through a heat exchanger where it is cooled to a temperature of 295k with negligible change in pressure. the valve can be modeled as a throttling process, and kinetic and potential energy effects can be neglected. (a) for a control volume enclosing the valve and heat exchanger and enough of the local surroundings that the heat transfer occurs at the ambient temperature of 295 k, determine the rate of entropy production, in kw/k. (b) if the expansion valve were replaced by an adiabatic turbine operating isentropically, what would be the entropy production? compare the results of parts (a) and (b) and discuss.

Apulley system is used to lift a 2,000 newton engine up a distance of 3 meters. the operator must apply a force of 250 newtons to the chain of the pulley system to lift the motor. to lift the engine 3 meters, the operator must pull a total of 30 meters of chain through the pulley system. what is the value of di?

Cathy is pedaling down a steep hill on her bicycle and wants to be able to coast up the next hill, which is 25 meters high, without pedaling. cathy and her bicycle have a mass of 75 kg. assuming her bicycle is 100% efficient, what would her speed have to be?