Which is heavier—warm air or cold air?

Consider the particle-in-a-box problem in 1d. a particle with mass m is confined to move freely between two hard walls situated at x = 0 and x = l. the potential energy function is given as (a) describe the boundary conditions that must be satisfied by the wavefunctions ψ(x) (such as energy eigenfunctions). (b) solve the schr¨odinger’s equation and by using the boundary conditions of part (a) find all energy eigenfunctions, ψn(x), and the corresponding energies, en. (c) what are the allowed values of the quantum number n above? how did you decide on that? (d) what is the de broglie wavelength for the ground state? (e) sketch a plot of the lowest 3 levels’ wavefunctions (ψn(x) vs x). don’t forget to mark the positions of the walls on the graphs. (f) in a transition between the energy levels above, which transition produces the longest wavelength λ for the emitted photon? what is the corresponding wavele

Calculate the work done by an external agent during an isothermal compression of 1.00 mol of oxygen from a volume of 22.4 l at 10∘c and 1.0 atm pressure to 16.8l

Air initially at 0.75 bar, 1000 k, and occupying a volume of 0.12 m^3 undergoes two processes. process 1-2: the air is compressed isothermally until the volume is halved. process 2-3: the air undergoes a constant pressure process until the volume is halved again. assume ideal gas behavior. a) determine the mass of the air, in kg. b) the work and the heat transfer for each of the two processes, in kj. (100 kj = 1 bar . m^3)