Refrigerant-134a at 400 psia has a specific volume of 0.1144 ft3/lbm. Determine the temperature of the refrigerant based on (a) the ideal-gas equation, (b) the van der Waals equation, (c) the refrigerant tables.

a) Using Ideal gas Equation, T = 434.98°R = 435°R

b) Using Van Der Waal's Equation, T = 637.32°R = 637°R

c) T obtained from the refrigerant tables at P = 400 psia and v = 0.1144 ft³/lbm is T = 559.67°R = 560°R

Explanation:

a) Ideal gas Equation

PV = mRT

T = PV/mR

P = pressure = 400 psia

V/m = specific volume = 0.1144 ft³/lbm

R = gas constant = 0.1052 psia.ft³/lbm.°R

T = 400 × 0.1144/0.1052 = 434.98 °R

b) Van Der Waal's Equation

T = (1/R) (P + (a/v²)) (v - b)

a = Van Der Waal's constant = (27R²(T꜀ᵣ)²)/(64P꜀ᵣ)

R = 0.1052 psia.ft³/lbm.°R

T꜀ᵣ = critical temperature for refrigerant-134a (from the refrigerant tables) = 673.6°R

P꜀ᵣ = critical pressure for refrigerant-134a (from the refrigerant tables) = 588.7 psia

a = (27 × 0.1052² × 673.6²)/(64 × 588.7)

a = 3.596 ft⁶.psia/lbm²

b = (RT꜀ᵣ)/8P꜀ᵣ

b = (0.1052 × 673.6)/(8 × 588.7) = 0.01504 ft³/lbm

T = (1/0.1052) (400 + (3.596/0.1144²) (0.1144 - 0.01504) = 637.32°R

c) The temperature for the refrigerant-134a as obtained from the refrigerant tables at P = 400 psia and v = 0.1144 ft³/lbm is

T = 100°F = 559.67°R

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