Why there is a shift in glass transition and thermal degradation temperature when nanoparticles are dispersed into a polymer?

For each of the following process: a) sketch the p-v diagram, b)sketch t-s diagram, c) sketch t-v diagram, d) sketch the boundary work on one of the diagrams (a, b or c) and e) sketch the reversible heat transfer on one of the diagrams (a, b or c): 1- isobaric process from compressed liquid to superheated vapor 2- isothermal process from compressed liquid to superheated vapor 3- isentropic process from compressed liquid to superheated vapor

Determine (a) the maximum thermal efficiency of reversible power cycles operating between a hot reservoir at 1000°c and a cold reservoir at 200°c and (b) the maximum cops for reversible refrigeration and heat pump cycies, respectively, between 28°c and 14°c.

Acircular pipe of 30mm outside diameter is placed in an airstream at 30 c and latm pressure. the air moves in cross flow over the pipe at 20 m/s, while the outer surface of the pipe is maintained at 110 c. what is the drag force exerted on the pipe per unit length? what is the rate of heat transfer from the pipe per unit length?