Which of the two gases, air or carbon dioxide, has the lower final temperature as it is expanded isentropically from 800 kpa and 400°c to 100 kpa in a piston-cylinder device. use room temperature specific heats.

In a unit cell of fcc structure, indicate the position of one of the tetrahedral interstitial sites by plotting the corresponding tetrahedron. do the same for one of the octahedral interstitial sites (in a separate fcc unit cell). mark the positions of all the tetrahedral and octahedral interstitial sites in the unit cells. how many equivalent tetrahedral sites and how many equivalent octahedral sites are contained in a fcc unit cell, respectively. what is the coordination number for a tetrahedral site and what is the coordination number for an octahedral site?