On solidification from a melt, the polymer polyethylene forms a semi-crystalline spherulite structure. (i) sketch an individual spherulite and label the amorphous and crystalline regions. (ii) draw a schematic to show the changes in specific volume with temperature during cooling from the melt, comparing it to the theoretical extremes of fully crystalline and fully amorphous (indicate tm and tg)

Agas contained within a piston-cylinder assembly e end nation about same energy states, 1 and 2, where pi 10 bar, v undergoes two processes, a and b, between the sam 0.1 m3, ui-400 kj and p2 1 bar, v2 1.0 m2, u2 200 kj: process a: process from 1 to 2 during which the pressure- volume relation is pv constant process b: constant-volume process from state 1 to a pressure of 2 bar, followed by a linear pressure-volume process to +20 0 state 2 kinetic and potential energy effects can be ignored. for each of the processes a and b, (a) sketch the process on p-v coordinates, (b) evaluate the work, in kj, and (c) evaluate process the heat transfer, in kj