Acompound composed of only carbon and chlorine is 85.5% chlorine by mass. propose a lewis structure for the lightest of the possible compounds that allows each atom to have a complete octet without formal charges. draw the molecule by placing atoms on the grid and connecting them with bonds. include all lone pairs of electrons.

Answer is in picture below.

Use 100 grams of the compound:

ω(Cl) = 85.5% ÷ 100%.

ω(Cl) = 0.855; mass percentage of the chlorine in the compound.

m(Cl) = 0.855 · 100 g.

m(Cl) = 85.5 g; mass of chlorine.

m(C) = 100 g - 85.5 g.

m(C) = 14.5 g; mass of carbon.

n(Cl) = m(Cl) ÷ M(Cl).

n(Cl) = 85.5 g ÷ 35.45 g/mol.

n(Cl) = 2.41 mol; amount of chlorine.

n(C) = 14.5 g ÷ 12 g/mol.

n(C) = 1.21 mol; amount of carbon.

n(Cl) : n(C) = 2.41 mol : 1.21 mol = 2 : 1.

This compound is dichlorocarbene CCl₂.

when 25.0 ml of 0.700 mol/l naoh was mixed in a calorimeter with 25.0 ml of 0.700 mol/l hcl, both initially at 20.0 °c, the temperature increased to 22.1 °c. the heat capacity of the calorimeter is 279 j/°c.

the equation for the reaction is:

naoh + hcl → nacl + h₂o

moles of hcl = 0.0250 l hcl ×

0.700

mol hcl

1 l hcl = 0.0175 mol hcl

volume of solution = (25.0 + 25.0) ml = 50.0 ml

mass of solution = 50.0 ml soln ×

1.00

ml soln

= 50.0 g soln

δt=t2-t1

= (22.1 – 20.0) °c = 2.1 °c

the heats involved are

heat from neutralization + heat to warm solution + heat to warm calorimeter = 0

q1+q2+q3=0

nδh+mcδt+cδt=0

0.0175 mol ×

δh

+ 50.0 g × 4.184 j·g⁻¹°c⁻¹ × 2.1 °c + 279 j°c⁻¹ × 2.1 °c = 0

0.0175 mol ×

δh

+ 439.32 j + 585.9 j = 0

0.0175 mol ×

δh

= -1025.22 j

δh=1025.22j0.0175 mol= -58 600 j/mol = -58.6 kj/mol