Chemistry, 25.11.2021 14:10, clarkster112679

Explain why one diastereomer is thermodynamically more stable than the other. To do so, draw both chair conformations for cis-4-tert-butylcyclohexanol. Do the same for trans-4-tert- butylcyclohexanol. Label all 1,3-diaxial interactions for these four species. Indicate the most stable chair conformation of cis-4-tert-butylcyclohexanol. Do the same for trans-4-tert-butyl- cyclohexanol. Which of these latter two species is the most stable

Answers: 2

Show answers

Answers

answered: Guest

answer: the value of enthalpy change will be -152.80 kj.

solution:

pressure = 1atm , temperature = $25^oc$ = 298 k $)0^oc=273kelvins$

$o_3+3no\rightarrow 3no_2,\delta h_{reaction}=? [/)</p><p>[tex]\delta h_{no}=90.4kj/mol$

$\delta h_{no_2}=33.85kj/mol$

$\delta h_{o_3}=142.2kj/mol$

$\delta h_{reaction}=\sum \delta h_{products}-\sum\delta h_{reactants}=3\times\delta h_{no_2}-(3\times \delta h_{no}+\delta h_{o_3})$

$\delta h_{reaction}=33.85-(90.4+142.2)=-311.85kj/mol$

given that pressure and temperature are same in both gases , the number of moles of both gases can be determined by the ideal gas equation.

$v_{no}=12.00 l,v_{o_3}=8.50 l$

$pv_{no}=n_{no}rt=1atm \times 12.00 l=n_{no}\times 0.0821 atml/k mol \times 298 k$

$n_{no}=0.49 moles$

$pv_{o_3}=n_{o_3}rt=1atm \times 8.50 l=n_{o_3}\times 0.0821 atml/k mol \times 298 k$

$n_{o_3}=0.34 moles$

according to reaction 3 moles no are reacting with 1 mol of $o_3$ ,then 0.49 mol of no will react with $\frac{1}{3}\times 0.49$ moles of ozone that is 0.16 moles of ozone. since, no is limiting reagent and $o_3$ is an excessive reagent.

enthalpy change for the reaction between the given volumes of the gases is :

$\delta h_{reaction}\times \text{moles of no}=-311.85kj/mol\times 0.49 mol=-152.80kj/mol$

answered: Guest

assuming that your periodic table has eighteen columns, you should highlight the four elements in the third column from the left of the table.

explanation

neutral atoms of elements after calcium contain d electrons. the energy of d orbitals of a particular main shell lies between the energy of the s and p orbitals of the next main shell. for example, electrons in the $3d$ have energy higher than those in the $4 s$ orbital while lower than those of the $4 p$ orbital.

by the aufbau principle, electrons fill orbitals one at a time, starting from those of the lowest energy. the $4s$ orbital is therefore filled right after $3p$ orbitals and before $3 d$ orbitals.

potassium has electron configuration $[\text{ar}] 4 s^{1}$ and calcium $[\text{ar}] 4 s^{2}$ . the s orbital of a main shell holds a maximum of two electrons. the next element would thus have the electron configuration $[\text{ar}] 4 s^{2} \; 3d^{1}$ and satisfy the requirements.

a neutral atom of the element contains three electrons on top of the most recent noble gas element. it should thus be placed in the third column of the periodic table. both scandium and yttrium would satisfy the conditions. an aufbau diagram indicates that the 4f orbital is filled before the 5d. however, it appears that exceptions exists for both lanthanum and actinium. neutral atoms of the two d-block elements also demonstrate the $ns^{2} \; (n-1) p^{1}$ and should be highlighted as well.

answered: Guest

the answer is:

line graphs show patterns in data with variables that change over time; whereas, circle graphs show data as parts out of a whole (such as out of 100%).

answered: Guest

gold is my favorite solid.

Other questions on the subject: Chemistry

Chemistry, 21.06.2019 21:00, yousifgorgees101

The earth's moon is unusually large. two popular theories of the moon's origin include the "sister world" hypothesis, which states that the moon formed from the same materials as the earth, near enough to the earth that they fell into orbit around each other. a second theory is the "capture" hypothesis, in which the moon formed elsewhere in the solar system, and the earth's gravity pulled it into its orbit. studies of what the moon is made of indicate that some of its materials had to come from the earth or from the same area of the solar system where the earth had formed. at the same time, the moon does not contain much of the material that makes up the earth's core, so the moon could not have formed from the same materials as the earth. how do the two facts above affect the described theories of the moon's origin? a. they show that scientists will never agree on where the moon came from. b. they show that more experiments on moon formation need to be done. c. they show that no theory accounts for the existence of the moon. d. they show that neither theory is complete and entirely correct.

Answers: 1

continue

Chemistry, 22.06.2019 12:30, MrSavannahCat

Clyde and marilyn are riding a roller coaster. during which section(s) of the track is their potential energy converted to kinetic energy? a. from point b to point c only b. from point b to point d only c. from point a to point b only d. from point a to point b and from point c to point d

Answers: 1

continue

Chemistry, 22.06.2019 16:20, kenia41

When water dissolves sugar, which process is not involved? o dissociation o hydration o surface area of the solute increases sa

Answers: 1

continue

Chemistry, 22.06.2019 22:30, pookie879

You just calculated that the heat of fusion for chloromethane is 6400 j/mol. the heat of fusion for hydrogen is 120 j/mol.? which of the following account for this difference? more than one correcta. chloromethane can absorb more energy at the same temperature. b. hydrogen has stronger intermolecular forces than chloromethane. c. hydrogen molecules can pack more closely than chloromethane molecules. d. chloromethane experiences dipole-dipole interactions. e. chloromethane has a higher molar mass than hydrogen.

Answers: 3

continue

Do you know the correct answer?

Explain why one diastereomer is thermodynamically more stable than the other. To do so, draw both ch...