Help me please it’s an emergency

Acalorimeter is to be calibrated: 51.203 g of water at 55.2 degree c is added to a calorimeter containing 49.783 g of water at 23.5c. after stirring and waiting for the system to equilibrate, the final temperature reached is 37.6 degree c. specific heat capacity of water (s = 4.18 j/g∙degree c). calculate the calorimeter constant. (smδt)warm water = -[(smδt)cold water + (calorimeterδtcold water)]

Which process results in the release of energy stored in the products of photosynthesis? a. polymer synthesis b. depolymerization c. digestion d. cellular respiration

110 g of water (specific heat = 4.184 j/g c) and 100 g of a metal sample (specific heat = 0.397 j/g c) are heated from 25 degrees c to 75 degrees c. which substance required more thermal energy?