PLEASE HELP ME IF YOU DO NOT KNOW DON'T ANSWER

(I'm sick at home, so my teacher wasn't able to teach me this... Also please do not just give a random answer, please answer it correctly)

Harvey kept a balloon with a volume of 348 milliliters at 25.0˚c inside a freezer for a night.  when he took it out, its new volume was 322 milliliters, but its pressure was the same.  if the final temperature of the balloon is the same as the freezer’s, what is the temperature of the freezer? the temperature of the freezer is  kelvins.

Which theory was contradicted by experiments with the photoelectric effect? light spreads out after it passes through a small opening. as soon as light strikes metal, electrons will be ejected. visible light, regardless of color, will cause the ejection of electrons when striking metal. the kinetic energy of ejected electrons depends on the frequency of light that strikes the metal.

A4.86 g piece of metal was placed in a graduated cylinder containing 15.5 ml of water. the water level rose to 17.3 ml. what is the density of the metal. i need the steps of how to solve it to so i can use a formula to work out other problems.