By using photons of specific wavelengths, chemists can dissociate gaseous HI to produce H atoms with certain speeds. When HI dissociates, the H atoms move away rapidly, whereas the heavier I atoms move more slowly. If a photon of 231 nm is used, what is the excess energy (in J) over that needed for dissociation

The excess energy over that needed for dissociation is 3.712 × 10⁻¹⁹ J

Explanation:

Given the data in the question;

wavelength of proton λ = 231 nm = 231 × 10⁻⁹ m

we determine the energy of the proton;

E = hc / λ

where h is plank constant ( 6.626 × 10⁻³⁴ JS )

and c is the speed of light ( 3 × 10⁸ m/s )

we substitute

E = [ ( 6.626 × 10⁻³⁴ JS ) × ( 3 × 10⁸ m/s ) ] / [ 231 × 10⁻⁹ m ]

E = 8.61 × 10⁻¹⁹ J

we know that, bond energy for H-I is 295 kJ/mol

so, H = 295 × 10³ J/mol

Now, energy to dissociate HI will be;

⇒ H / N

where N is the Avogadro's number ( 6.023 × 10²³ mol⁻¹ )

energy to dissociate HI = ( 295 × 10³ J/mol ) / ( 6.023 × 10²³ mol⁻¹ )

= 4.898 × 10⁻¹⁹ J

Therefore, Excess energy over dissociation will be;

⇒ ( 8.61 × 10⁻¹⁹ J ) - ( 4.898 × 10⁻¹⁹ J )

= 3.712 × 10⁻¹⁹ J

The excess energy over that needed for dissociation is 3.712 × 10⁻¹⁹ J

gravity causes stares to cluster i think so

1. the question asks the most appropriate, which seems to rule out "all of the above." your choice appears to be the correct one.

2. the protocol described is good for identifying correlation, but not cause and effect. for cause/effect, you need to devise a protocol that will assign the treatment (or not) to groups that have essentially the same "demographics" with respect to all the other variables. your choice regarding control group seems appropriate. random assignment of treatment (choice d) may be appropriate also. (i think you can argue that b and d are just different descriptions of the same method.)

3. d will randomize the birds, but may not guarantee there are 10 in each group. e will do both, so seems the better choice.

comment on question 2

based on the problem statement, it seems clear that confident, attentive drivers are more likely to use daytime running lights. so, the protocol might need to be devised in such a way that the lights would be turned on or off without the driver's knowledge. (an attentive driver will figure it out.) assigning a confident, attentive driver to a group required to drive without running lights might mess with his/her confidence and attentiveness. you don't want your experiment to do that. (nor do you want the experiment to subject a driver to greater risk of accident as a consequence of driving without running lights.) experiments involving human safety are always problematic.