Hii pls help me to balance the equation and state the symbols thanksss​

Need on both questionswill markbr />

Kp is the equilibrium constant for dissociation of the propionic acid dimer. what is the sign of the slope for a plot of the natural logarithm of kp vs. inverse temperature for this reaction?

Liquid from a brewery fermentation contains 10% ethanol and 90% water. part of the fermentation product (50,000 kg/h) is pumped to a distillation column on the factory site. under current operating conditions, a distillate of 45% ethanol and 55% water is produced from the top of the column at a rate of one-tenth that of the feed. what is the composition of the waste "bottoms" from the still?