Poly(ethylene terephthalate) (PET), which has glass transition (Tg) and crystalline melting (Tm) temperature of 69 and 267 °C, respectively, can exist in a number of different states depending upon temperature and thermal history. Thus, it is possible to prepare materials that are semicrystalline with amorphous regions that are either glassy or rubbery and amorphous materials that are glassy, rubbery or melts. Consider a sample of PET cooled rapidly from 300 °C (state A) to room temperature. The resulting material is rigid and perfectly transparent (state B). The sample is then heated to 100 °C and maintained at this temperature, during which time is gradually becomes translucent (state C). It is then cooled to room temperature, where it is again observed to be translucent (state D).

Following are the solution to the given points:

Explanation:

For point A:

For point B:

In point 3, the mixture was added to 100°C, which implies that the granular material flows and deforms, enabling it to become elongated. This is termed solid-state crystalline such that grains are flexible, but this material contaminates numerous little crystalline that has spheres when we cool down in point  4 polymers. It forms therefore an unstructured solid, which then in point 4 is higher in particles and less pliable in orderly atoms.

For point C:

In point 2, the specimen gets forced at room temperature to organize a huge molecule in an ordinary and crystal fashion and therefore is transparent due to highly crystalline atoms in point 2 of the PET sample.

In point 4, however, we notice how amorphous, firm but not crystalline develops. It's why light tends to disperse over many cereal limits, since many microscopic crystallines, therefore dispersion, PET in point 4 is translucent.

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definition

                    entropy is a measure of the randomness or the extent of disorder of a chemical process.

                      enthalpy is a measure of the heat change of a reaction occurring at a constant pressure.

measurement units:

                        entropy is measured in joule per kelvin (jk⁻¹)   whereas enthalpy is measured in joule per mole (jmol⁻¹)

requirements:

                            entropy has no requirements or limits, and its change is measured by the division between the heat change of the chemical process and the temperature.

                              in contrast, enthalpy can only be related to the heat change of the reaction under standard conditions.