(c). The first ionisation energy of Cl in gaseous atom is 1251 kJ mol-1 whereas 125
the electron affinity of Cl is -349 kJ mol-1. Explain clearly the changes of
energy associated with the process by providing their balanced chemical
equations.

the correct answer is:

a. formation of precipitation

answer: - first one is the correct answer. .

explanations: - potassium sulfide is and cobalt(ii) chloride is .

charge on k is +1, charge on s is -2, charge on co is +2 and charge on cl is -1.

in a double replacement reaction the ion exchange takes place. in general the reaction looks like:

if one of the product is insoluble as per solubility rules then a precipitate of it is formed.

when we mix the aqueous solutions of potassium sulfide and cobalt(ii) chloride then chloride ion goes with potassium ion and sulfide ion goes with cobalt ion and the balanced equation is written as:

k and cl has equal charges, similarly co and s has equal charges and hence no subscripts are used for the product side.

as per the solubility rules, cos is insoluble and so it's precipitate is formed.

looking at the given choices, first choice is correct.