Calculate the pH of a 0.500 M aqueous solution of NH3 . The Kb of NH3 is 1.77x10-5

Can someone me with questions 12 and 13 plz.

How many mmols of tris-hcl are there in 100 ml of a 100 mm tris-hcl buffer solution at ph 8.1? note that the 100 mm refers to the sum of tris and tris-hcl concentrations?

Phosphorous acid, h3po3(aq) , is a diprotic oxyacid that is an important compound in industry and agriculture. p k a1 p k a2 1.30 6.70 calculate the ph for each of the points in the titration of 50.0 ml of 1.5 m h3po3(aq) 1.5 m h 3 po 3 ( aq ) with 1.5 m koh(aq). 1.5 m koh ( aq ) .