54.56 g of water at 80.4 oC is added to a calorimeter that contains 47.24 g of water at 40 oC. If the final temperature of the system is 59.4 oC, what is the calorimeter constant (C calorimeter)

49.5J/°C

Explanation:

The hot water lost some energy that is gained for cold water and the calorimeter.

The equation is:

Q(Hot water) = Q(Cold water) + Q(Calorimeter)

Where:

Q(Hot water) = S*m*ΔT = 4.184J/g°C*54.56g*(80.4°C-59.4°C) = 4794J

Q(Cold water) = S*m*ΔT = 4.184J/g°C*47.24g*(59.4°C-40°C) = 3834J

That means the heat gained by the calorimeter is

Q(Calorimeter) = 4794J - 3834J = 960J

The calorimeter constant is the heat gained per °C. The change in temperature of the calorimeter is:

59.4°C-40°C = 19.4°C

And calorimeter constant is:

960J/19.4°C =

here we have to get the change of moles on decrease the volume of the reaction in gas phase.

the   per the given options it will decrease by (d) 11-50%

we know, on decreasing the volume of the gas phase reaction the reaction moves to the product side.

the reaction:                     so₂cl₂ (g) = so₂ (g) + cl₂ (g)         total

the moles at equilibrium:   1 - α                 α               α           = 1+α

concentrations:                   1 - α               α               α           = 1 + α

(concentration = moles/volume, as volume is 1 l)

(where α is the degree of dissociation)

now the dissociation constant in terms of concentration is :

=  

or,

or,   = (at v = 1l)

the reaction:                     so₂cl₂ (g) = so₂ (g) + cl₂ (g)         total

the moles at equilibrium:   1 - α                 α               α           = 1+α

concentrations:               (1 - α)/0.5           α/0.5         α/0.5       = (1 + α)/0.5

thus, the dissociation constant in terms of concentration is :

or,  

=  

so, the change of 1 : 1/0.5

or, 1: 2

thus it will decrease by 50%.

or, as per the given options it will decrease by 11-50%

answer; economic order quantity;