Equilibrium constants for gases can be expressed in terms of concentrations, Kc, or in terms of partial pressures, Kp. Which one of the following statements regarding Kc and Kp is correct? a. Kc and Kp are equal when all stoichiometric coefficients in the balanced reaction equation equal one.
b. Kc and Kp are equal when the conditions are standard (P= 1 atm, T=298 K)
c. Kc and Kp are equal when the sum of the stoichiometric coefficients for the products equals the sum of the stoichiometric coefficients for the reactants.
d. Kc and Kp can never be equal.
e. Kc and Kp have the same values but different units.

c. Kc and Kp are equal when the sum of the stoichiometric coefficients for the products equals the sum of the stoichiometric coefficients for the reactants.

Explanation:

Hello there!

In this case, according to the given information, it turns out firstly necessary for us to write the relationship between Kc and Kp in terms of the temperature and the change in the stoichiometric coefficients:

Thus, we can see that the Kp=Kc just when Δυ=0, which is the sum of the coefficients of products minus that of reactants; and therefore, the correct answer will be c. Kc and Kp are equal when the sum of the stoichiometric coefficients for the products equals the sum of the stoichiometric coefficients for the reactants.

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when the volume of gas is   changed from   717.73 ml   to 852 ml   the temperature will   change   from 315   c to 452   c

    calculation

this is calculated using the charles law formula

that is,   v1/t1 = v2/t2

          v1=?

        t1 = 315 c   into   kelvin = 315 +273 = 588 k

        v2 = 852   ml

        t2 = 425c + 273 =698 k

make v1   the subject of the formula ( by   multiplying both side by t1)

  v1=( v2 xt1) / t2

v1= (852 ml   x 588 k)/ 698 k= 717.73 ml

it is the most commonly accepted one