HCHO Practice Exercise 1
We have just arrived at a bonding description for the formalde-
hyde molecule. Which of the following statements about the
molecule is or are true?

(i) Two of the electrons in the molecule are used to make the
Pie bond in the molecule.
(ii) Six of the electrons in the molecule are used to make the o
bonds in the molecule.

(iii) The C-O bond length in formaldehyde should be shorter
than that in methanol, H3COH.
(a) Only one of the statements is true.
(b) Statements (i) and (ii) are true.
(c) Statements (i) and (iii) are true.
(d) Statements (ii) and (iii) are true.
(e) All three statements are true

when 25.0 ml of 0.700 mol/l naoh was mixed in a calorimeter with 25.0 ml of 0.700 mol/l hcl, both initially at 20.0 °c, the temperature increased to 22.1 °c. the heat capacity of the calorimeter is 279 j/°c.

the equation for the reaction is:

naoh + hcl → nacl + h₂o

moles of hcl = 0.0250 l hcl ×

0.700

mol hcl

1 l hcl = 0.0175 mol hcl

volume of solution = (25.0 + 25.0) ml = 50.0 ml

mass of solution = 50.0 ml soln ×

1.00

ml soln

= 50.0 g soln

δt=t2-t1

= (22.1 – 20.0) °c = 2.1 °c

the heats involved are

heat from neutralization + heat to warm solution + heat to warm calorimeter = 0

q1+q2+q3=0

nδh+mcδt+cδt=0

0.0175 mol ×

δh

+ 50.0 g × 4.184 j·g⁻¹°c⁻¹ × 2.1 °c + 279 j°c⁻¹ × 2.1 °c = 0

0.0175 mol ×

δh

+ 439.32 j + 585.9 j = 0

0.0175 mol ×

δh

= -1025.22 j

δh=1025.22j0.0175 mol= -58 600 j/mol = -58.6 kj/mol

each chemical family is represented as a group or column on the periodic table. based on chemical properties, there are 6 types of chemical families. group 1 represents alkali metals, group 2 represents alkaline earth metals, groups 3 to 12 represent transition metals, groups 13 to 16 represent non-metals and other metals, group 17 represents halogens and group 18 represents noble gases.