Calculate the ΔH for the following reaction: (15 pts) 3 Fe2O3+ Co → 2Fe304 + CO2
Given the following information:
Fe2O3 + 3 CO → 2 Fe 3 CO2
ΔH = -5.7KJ
Fe3O4 + CO → 3FeO + CO2
ΔH = -4.5KJ
Fe + CO2 → FeO + CO
ΔH = -0.3KJ

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answer : (a) volume of the gas = 8.67 ×   l

                (b) second virial coefficient b = -1.21226 l/mole

solution :   given,     t = 300k

                                p = 20atm

                                z = 0.86

                                n = 8.2 mmoles = 8.2 × moles

                                r =   0.082 l atm/k/mol

        find,     (a) volume of gas   and (b) second virial coefficient b at 300k.

formula used :            

                          and            

(a)            

                    = \times 0.082\times 300}{20}[/tex]

                    = 8.67 ×   l

(b)      

                    = (0.00867-1) × 8.659

                    = - 8.5839 l/mole