PLEASE help with these two! I have no idea

What amount of heat is exchanged when 106.2 grams of substance y goes from a liquid at 35 degrees celsius to a solid at the same temperature? melting point of substance y = 35 degrees c; δhvaporization = 3.67 j/mol; δhfusion = 3.30 j/mol. mwsubstance y = 28.22 g/mol. −12.4 j −3.51 x 102 j 1.24 x 101 j 351 j

Athe top of a hill, an athlete on a skateboard has x joules of mechanical energy. how much mechanical energy will she have at the bottom of the hill? ignore the effects of friction.

The activation energy for this reaction is 75 kj·mol–1. the enzyme catalase (found in blood) lowers the activation energy to 8.0 kj·mol–1. at what temperature would the non-catalyzed reaction need to be run to have a rate equal to that of the enzyme-catalyzed reaction at 25°c?