Question to pomis) A metal tank contains four gases: oxygen, helium, argon, and nitrogen. If the partial pressures of the three gases in the tank
are 35 atm of O2, 5 atm of N2, and 25 atm of He and the total pressure is 66 atm, what is the partial pressure of argon
inside of the tank?

the formula mass of a molecule or a compound is the sum of the atomic weights of the atoms in its empirical formula

(that's what i know about formula mass)

hydrocarbons are organic compounds that contain only hydrogens and carbons. they can be saturated (those which contain only carbon-carbon single bonds) or unsaturated (those which contain carbon-carbon double or triple bonds) in nature. hydrocarbons can undergo several reactions like substitution, elimination etc.  

on substituting one or more hydrogen atoms in hydrocarbon it results in the formation of haloalkane. as the halogen atoms are large compared to the carbon and hydrogen atoms, due to which the molecular weight increases and the bond become polar because of presence electronegative halogen atom and results in the increase in boiling point of the haloalkane.

thus, the correct option is (b) that is the boiling point of the new compound increases on substituting a hydrogen atom with a halogen in a hydrocarbon.