To a good approximation, the hydrogen chloride molecule, HCl, behaves vibrationally as a quantum harmonic oscillator of spring constant 480 N/m and with effective oscillating mass just that of the lighter atom, hydrogen. If it were in its ground vibrational state, what wavelength photon would be just right to bump this molecule up to its next-higher vibrational energy state

For cyclohexane compounds drawn in a chair conformation:   -axial bonds are vertical  -equatorial bonds are parallel to two bonds within the ring.  thus, as i assume the chair conformation is drawn:   -the x group is in an axial position, as are the five other vertical bonds.  -three axial bonds are on the top face of the ring  -the other three axial bonds are on the bottom face  the position of the second substituent on each ring carbon is equatorial.  gauche groups must be on an adjacent carbon such as carbon 6 and carbon 2, and also gauche groups are rotated by 60 degrees relative to each other.  drawing the newman projections for c1–c2 and c1–c6 aids in visualizing the groups that are gauche to the y group on c1.  click this link and watch some academic videos that may you more understand the topic 

Ans. : frostbite is when exposure to cold temperatures causes freezing to the skin or other tissues. it most commonly affects the hands, feet, and face. the longer areas are exposed to cold, typically the worse the frostbite. the water temperature used for rewarming a frostbitten part should be : (102 -105) f degrees.