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The free-electron model of metals assumes that the outermost valence electrons of each atom are free to roam about the metal. In its simplest form, the metal is modeled as a box with zero potential energy inside and infinite potential energy outside. To describe the behavior of electrons in such a potential, we need to determine the allowed quantum states and how the electrons are distributed among those states. The number of quantum states available with energies
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The free-electron model of metals assumes that the outermost valence electrons of each atom are free...
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