Asample of hydrogen gas has a volume of 4.4l at a pressure of 800torr. if the pressure in decreased to 400 torr, what will be the new volume

V₂ = 8.8 L

Explanation:

A sample of hydrogen has a volume V₁ = 4.4 L at a pressure P₁ = 800 torr. If we decrease the pressure to P₂ = 400 torr, we can find the new volume (V₂) using Boyle's law (assuming the temperature remains constant and the gas behaves as an ideal gas).

P₁ × V₁ = P₂ × V₂

800 torr × 4.4 L = 400 torr × V₂

V₂ = 8.8 L

when 25.0 ml of 0.700 mol/l naoh was mixed in a calorimeter with 25.0 ml of 0.700 mol/l hcl, both initially at 20.0 °c, the temperature increased to 22.1 °c. the heat capacity of the calorimeter is 279 j/°c.

the equation for the reaction is:

naoh + hcl → nacl + h₂o

moles of hcl = 0.0250 l hcl ×

0.700

mol hcl

1 l hcl = 0.0175 mol hcl

volume of solution = (25.0 + 25.0) ml = 50.0 ml

mass of solution = 50.0 ml soln ×

1.00

ml soln

= 50.0 g soln

δt=t2-t1

= (22.1 – 20.0) °c = 2.1 °c

the heats involved are

heat from neutralization + heat to warm solution + heat to warm calorimeter = 0

q1+q2+q3=0

nδh+mcδt+cδt=0

0.0175 mol ×

δh

+ 50.0 g × 4.184 j·g⁻¹°c⁻¹ × 2.1 °c + 279 j°c⁻¹ × 2.1 °c = 0

0.0175 mol ×

δh

+ 439.32 j + 585.9 j = 0

0.0175 mol ×

δh

= -1025.22 j

δh=1025.22j0.0175 mol= -58 600 j/mol = -58.6 kj/mol