calculate the molarity of the chloride ions present in a 0.20% (w/v) calcium chloride solution (CaCl2)​

The problem here is that according to aufbau principle before 3d orbital 4s subshell comes.after filling 3p orbital with electrons you have 4 electrons left, you place two in 4s with opposite spin and the other two in 3d in any of its two orbitals of total five orbitals with the same spin.

There are no metaphors.

Given data,temperature, t = 230°c = 503 kconsider the chemical reaction,ch₃oh(l) + 1/2 o₂(g)  → ch₂o(g) + h₂o(l)calculate the enthalpy change for the reaction: δh⁰rxn =  σnδh⁰f(products) -  σmδh⁰f(reactants)substitute the values from the table: δh⁰rxn = { -115.9 + (-285.8)} - {0+(-238.7)}              = -163.0 kjcalculate the entropy change for the reaction.δs⁰rxn = (219 + 70) - (127.2 + 1/2 x 205.2) = 59.2 j/kconsider the expression for free energy: δg⁰rxn =  δh⁰rxn - t  δs⁰rxnsubstitute the values in the above equationδg⁰rxn = -163 x 10³ - (503 x 59.2)              = -192777.6 j              = -192.777 kj