Titanium is a transition metal used in many alloys because it is extremely strong and lightweight. Titanium tetrachloride (TiCl4) is extracted from titanium oxide using chlorine and coke (carbon). TiO2(s) + C(s) + 2 Cl2(g) TiCl4(s) + CO2(g) (a) What mass of Cl2 gas is needed to react with 1.60 mol TiO2? g (b) What mass of C is needed to react with 1.60 mol of TiO2? g (c) What is the mass of all the products formed by reaction with 1.60 mol of TiO2? g

a) 226.6 grams of Cl₂

b) 19.2 grams of C

c) 303.2 grams of TiCl₄ and 70.4 grams of CO₂

Explanation:

The balanced chemical reaction is the following:

TiO₂(s) + C(s) + 2 Cl₂(g) → TiCl₄(s) + CO₂(g)

(a) What mass of Cl₂ gas is needed to react with 1.60 mol TiO₂?

From the chemical equation, 1 mol of TiO₂ reacts with 2 moles of Cl₂. So, the stoichiometric ratio is 2 mol Cl₂/1 mol TiO₂. We multiply this ratio by the moles of TiO₂ we have to calculate the moles of Cl₂ we need:

1.60 mol TiO₂ x 2 mol Cl₂/1 mol TiO₂ = 3.2 mol Cl₂

Now, we convert from moles to mass by using the molecular weight (MW) of Cl₂:

MW(Cl₂) = 35.4 g/mol x 2 = 70.8 g/mol

mass of Cl₂= 3.2 mol x 70.8 g/mol = 226.6 g

Therefore, 226.6 grams of Cl₂ are needed to react with 1.6 mol of TiO₂.

(b) What mass of C is needed to react with 1.60 mol of TiO₂?

From the chemical equation, 1 mol of TiO₂ reacts with 1 moles of C(s). So, the stoichiometric ratio is 1 mol C/1 mol TiO₂. We multiply this ratio by the moles of TiO₂ we have to calculate the moles of C(s) we need:

1.60 mol TiO₂ x 1 mol C(s)/1 mol TiO₂ = 1.60 mol C(s)

So, we convert the moles of C(s) to grams as follows:

MW(C) = 12 g/mol

1.60 mol x 12 g/mol = 19.2 g C(s)

Therefore, a mass of 19.2 grams of C is needed to react with 1.60 mol of TiO₂.

(c) What is the mass of all the products formed by reaction with 1.60 mol of TiO₂?

From the chemical equation, we can notice that 1 mol of TiO₂ produces 1 mol of TiCl₄ and 1 mol of CO₂. So, from 1.60 moles of TiO₂, 1 mol of each product will be produced:

1 mol TiO₂/1 mol TiCl₄ ⇒ 1.60 mol TiO₂/1.60 mol TiCl₄

1 mol TiO₂/1 mol CO₂ ⇒ 1.60 mol TiO₂/1.60 mol CO₂

Finally, we convert the moles to grams by using the molecular weight of each compound:

MW(TiCl₄) = 47.9 g/mol Ti + (35.4 g/mol x 4 Cl) = 189.5 g/mol

1.60 mol x 189.5 g/mol = 303.2 g

MW(CO₂) = 12 g/mol C + (16 g/mol x 2 O) = 44 g/mol

1.60 mol x 44 g/mol = 70.4 g

Therefore, from the reaction of 1.60 mol of TiO₂ are formed 303.2 grams of TiCl₄ and 70.4 grams of CO₂.

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