Help on question 22 and 23 please??

Blank allows you to do calculations for situations in which only the amount of gas is constant a)boyle's law b)combined gas law c)ideal gas law d)dalton's law

Why is the bond angle in a water molecule less than the bond angle of methane? a. the central oxygen atom in water has two lone pairs of electrons, whereas the central carbon atom in methane has no lone pairs. b. the central hydrogen atom in water has one lone pair of electrons, whereas the central carbon atom in methane has two lone pairs. c. the central oxygen atom in water has four lone pairs of electrons, whereas the central carbon atom in methane has only one lone pair. d. the central oxygen atom exerts more repulsive force on surrounding atoms than the central carbon atom in methane does. reset next

The reactions shown here can be combined to make the overall reaction c(s) + h2o(g) ⇌ co(g) + h2(g) by reversing some and/or dividing all the coefficients by a number. a. c(s) + o2(g) → co2(g) k=1.363×10^69 b. 2 h2(g) + o2(g) → 2 h2o(g) k=1.389×10^80 c. 2co(g) + o2 (g) → 2 co2(g) k=1.477×10^90