A small amount of liquid bromine is added to a container which is then sealed. Br2 (l) " Br2 (g)

Br2(i) would be sealed due to my calculations

Reaction involved in present system is :   c12h22o11 + h2o → 2 c6h12o6the reaction system is obeying following rate law:   rate = k[c12h22o11]thus, it is a first order reaction.now, for 1st order reactionrate constant (k) =  given: initial conc. = 3.0 g, final conc. = 2.7 g, t = 2.5 h∴rate constant (k) =  ∴ k = 0.04215 h-1now, for 1st order reaction, half life = 0.693/k = 0.693/0.04215 = 16.4 hthus correct answer is option b

  the volume of  0.220 m k2s    solution  required  to  completely  react with 175 ml  of 0.115m co(no3)2  calculate the moles  of co(no3)2 =  molarity x volume/1000175 x0.115/1000= 0.02  moleswrite  the reacting  equationk2s(aq)  +  co(no3)2  = 2 kno3(aq)  + cos(s)by  use  of mole ratio between k2s to co(no3)2 which  is  1: 1 the moles of k2s is therefore = 175  x0.115/1000= 0.02  molesvolume = moles/molarity=0.02/0.22=0.09  ml  of k2s