A compound is known to have a free amino group with a pKa of 8.8, and one other ionizable group with a pKa between 5 and 7. To 100 mL of a 0.2 M solution of this compound at pH 8.2 was added 40 mL of a solution of 0.2 M hydrochloric acid. The pH changed to 6.2. The pKa of the second ionizable group is:

if the concentration of products is decreased, the equilibrium will shift toward the products). add an inert gas (one that is not involved in the reaction) to the constant-volume reaction mixture: this will increase the total pressure of the system, but will have no effect on the equilibrium condition.

explanation:

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