Please help me with this, thank you so much

Predict whether the changes in enthalpy, entropy, and free energy will be positive or negative for the boiling of water, and explain your predictions. how does temperature affect the spontaneity of this process?

13. a covalent bond between two atoms is likely to be polar if: a. one of the atoms is much more electronegative than the other. b. the two atoms are equally electronegative. c. the two atoms are of the same element. d. the bond is part of a tetrahedrally shaped molecule. e. one atom is an anion.

Answer asap need it by wednesday morning carry out the following calculations on ph and ka of from data. i. calculate the ph of 0.02m hcl ii. calculate the ph of 0.036m naoh iii. calculate the ph of 0.36m ca(oh)2 iv. calculate the ph of 0.16m ch3cooh which has ka = 1.74 x 10-5 mol dm-3 v. calculate ka for weak acid ha which has a ph of 3.65 at 0.30m concentration vi. calculate the ka of a solution made by mixing 15.0 cm3 0.2m ha and 60.0 cm3 0.31m a-. [ph= 3.80] vii. calculate the ph of a solution made by mixing 15.0 cm3 0.1m naoh and 35.0 cm3 0.2m hcooh. [ka = 1.82 x 10-4 m]