I need the answers for question 2 and3

Which theory was contradicted by experiments with the photoelectric effect? light spreads out after it passes through a small opening. as soon as light strikes metal, electrons will be ejected. visible light, regardless of color, will cause the ejection of electrons when striking metal. the kinetic energy of ejected electrons depends on the frequency of light that strikes the metal.

Match the formula for the following compound:   magnesium sulfate heptahydratemgs·7h2omg2so4·7h2omg(s o4)2·7h2omgso4·7h2o

Which orbitals form a pi bond? a. the s orbital and three p orbitals b. the s orbital and two p orbitals c. overlapping p orbitals d. overlapping hybrid orbitals