What volume of a 0.100 M AgNO3 solution is required to completely react with the CaCl2 in 3.00 L of a 0.100 M CaCl2 solution? The balanced chemical equation is: 2 JUpper A g upper N upper 0 subscript 3 plus upper C a upper C l subscript 2 right arrow 2 upper A g upper C l plus upper C a (upper N upper O subscript 3) subscript 2. L AgNO3

the electronic configuration of an atom with eight electrons is 1s²2s²2p⁴. the orbital diagrams are shown in the figure.

as per the hunds rule:

1. electrons tend to avoid being in the same orbital as per as practicable.

2. electrons in different orbitals of the same energy will have their spin parallel.

this can be illustrated from the multiplicity of the orbitals of the atom. as there are four electrons in the p orbital and p orbital has 3 sub-shells. the electrons can be fed in different ways as shown in the figure but the correct orbital diagram will be as per the hunds rule.

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when 25.0 ml of 0.700 mol/l naoh was mixed in a calorimeter with 25.0 ml of 0.700 mol/l hcl, both initially at 20.0 °c, the temperature increased to 22.1 °c. the heat capacity of the calorimeter is 279 j/°c.

the equation for the reaction is:

naoh + hcl → nacl + h₂o

moles of hcl = 0.0250 l hcl ×

0.700

mol hcl

1 l hcl = 0.0175 mol hcl

volume of solution = (25.0 + 25.0) ml = 50.0 ml

mass of solution = 50.0 ml soln ×

1.00

ml soln

= 50.0 g soln

δt=t2-t1

= (22.1 – 20.0) °c = 2.1 °c

the heats involved are

heat from neutralization + heat to warm solution + heat to warm calorimeter = 0

q1+q2+q3=0

nδh+mcδt+cδt=0

0.0175 mol ×

δh

+ 50.0 g × 4.184 j·g⁻¹°c⁻¹ × 2.1 °c + 279 j°c⁻¹ × 2.1 °c = 0

0.0175 mol ×

δh

+ 439.32 j + 585.9 j = 0

0.0175 mol ×

δh

= -1025.22 j

δh=1025.22j0.0175 mol= -58 600 j/mol = -58.6 kj/mol

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