How many moles of NO2 are needed to increase the temperature of a 333 gram block of iron from 220C to 13000C? (specific heat of iron is 0.49 J/g0C) 3NO2 + H2O --> 2HNO3 + NO ∆H = - 138 kJ /mol

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answer : third trial had the contaminated sample and the correct value for dhrxn should be 1000 kj/mol

explanation :

let us write down the given equations

equation 1 :

equation 2 :

equation 3 :

let us use hess's law to find out which 2 equations can be added to get the third equation.

let us reverse equation 2 and multiply it by 2. the new equation that we get is,

equation 4 :

let us add equation 1 & 4

the above equation is similar to equation 3 but has different value for dhrxn.

therefore third trial had the contaminated sample and the correct value for dhrxn should be 1000 kj/mol

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