13. Explain why changes in the concentrations of the reactants and products at equilibrium have no effect
on the value of the equilibrium constant.

1. suppose a reaction mixture, when diluted with water, afforded 300 ml of an aqueous solution of 30 g of the reaction product malononitrile [ch2(cn)2], which is to be isolated by extraction with ether. the solubility of malononitrile in ether at room temperature is 20.0 g/100 ml, and in water is 13.3 g/100 ml. what weight of malononitrile would be recovered by extraction with (a) three 100-ml portions of ether and (b) one 300-ml portion of ether? suggestion: for each extraction, let x equal the weight extracted into the ether layer. in part (a), the concentration in the ether layer is x/100 and in the water layer is (30 x)/300; the ratio of these quantities is equal to k 20/13.3.

Nanotechnology, the field of trying to build ultrasmall structures one atom at a time, has progressed in recent years. one potential application of nanotechnology is the construction of artificial cells. the simplest cells would probably mimic red blood cells, the body's oxygen transporters. for example, nanocontainers, perhaps constructed of carbon, could be pumped full of oxygen and injected into a person's bloodstream. if the person needed additional oxygen-due to a heart attack perhaps, or for the purpose of space travel-these containers could slowly release oxygen into the blood, allowing tissues that would otherwise die to remain alive. suppose that the nanocontainers were cubic and had an edge length of 24 nanometers. part a part complete what is the volume of one nanocontainer? (ignore the thickness of the nanocontainer's wall.) express your answer using two significant figures. v v = 1.4ă—10â’20 l previous answers correct significant figures feedback: your answer 1.3824â‹…10â’20 = 1.382ă—10â’20 l was either rounded differently or used a different number of significant figures than required for this part. if you need this result for any later calculation in this item, keep all the digits and round as the final step before submitting your answer. part b suppose that each nanocontainer could contain pure oxygen pressurized to a density of 81 g/l . how many grams of oxygen could be contained by each nanocontainer?

Aman applies a force of 500n to push a truck 100m down the street how much does he do?