Chemistry, 14.11.2020 03:00, izzygewin47821

4. A 300 mL sample of a gas at a temperature of 400 K exerts a pressure of exactly one atmosphere. What pressure does the gas exert when the volume
decreases to 200 mL and the temperature increases to 600 K?

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answered: Guest

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answered: Guest

answer : third trial had the contaminated sample and the correct value for dhrxn should be 1000 kj/mol

explanation :

let us write down the given equations

equation 1 : $4x (s) + 3o_{2} (g) \rightarrow 2x_{2}o_{3} (s) h rxn = -600 kj/mol$

equation 2 : $2x (s) + 3cl_{2} (g) \rightarrow 2xcl_{3} (s) h rxn = -800 kj/mol$

equation 3 : $4xcl_{3} (s) + 3o_{2} (g) \rightarrow 2x_{2}o_{3} (s) + 6cl_(2} h rxn = -200 kj/mol$

let us use hess's law to find out which 2 equations can be added to get the third equation.

let us reverse equation 2 and multiply it by 2. the new equation that we get is,

equation 4 : $4xcl_{3} (s) \rightarrow 4x (s) + 6cl_{2} ( h rxn = (+800) \times 2 kj/mol$

let us add equation 1 & 4

$4x (s) + 3o_{2} (g) \rightarrow 2x_{2}o_{3} (s) h rxn = -600 kj/mol$

$4xcl_{3} (s) \rightarrow 4x (s) + 6cl_{2} ( h rxn = (+1600) kj/mol$

$4xcl_{3} )s) + 3o_{2} \rightarrow 2x_{2}o_{3} (s) + 6cl_{2} (g) h rxn = (+1000) kj/mol$

the above equation is similar to equation 3 but has different value for dhrxn.

therefore third trial had the contaminated sample and the correct value for dhrxn should be 1000 kj/mol

answered: Guest

Answer ozone (o3) is made of three atoms of oxygen, it is a molecule;

answered: Guest

the missing options are :

(1) lower boiling point and a lower freezing point(2) lower boiling point and a higher freezing point(3) higher boiling point and a lower freezing point(4) higher boiling point and a higher freezing point

answer : the correct answer is option (3) higher boiling point and a lower freezing point

explanation :

when a non volatile solute is added to a solvent like water, it results in elevation of boiling point.

let us find the increase in boiling point of water when cacl₂ is added to water to make a solution of 1 m

step 1 : find molality of the solution

let us assume we have 1 l of solution.

$m = \frac{moles (solute)}{l ( solution)}$

$1 m = \frac{moles (cacl_{2})}{1 l }= 1 mol cacl_{2}$

let us convert this to grams of cacl₂.

molar mass of cacl2 is 111 g/mol

grams of cacl₂ = $1 mol \times \frac{111g}{mol} = 111 g cacl_{2}$

mass of solute = 111 g

assuming density of solution same as water which is 1g/ml we have ,

mass of solution = density * volume

mass of solution = $\frac{1g}{ml} \times 1000 ml = 1000 g$

mass of solution = mass of solvent + mass of solute

mass of solute = 1000g - 111g

mass of solute 889 g = 0.889 kg

the molality of the solution can be calculated as

$molality = \frac{mol (solute)}{kg ( solvent)}$

$molality = \frac{1mol}{0.889kg}$

molality = 1.12 m

step 2 : find boiling point elevation.

the elevation in boiling point is calculated as

$\bigtriangleup t_{b} = i \times k_{b} \times m$

here δtb = boiling point elevation

i = vant hoff factor which is the number of ions formed by the solute .

cacl₂ dissociates as $cacl_{2} \rightarrow ca^{2+} + 2 cl^{-}$

it forms 3 ions . therefore,

i = 3

m = molality which is 1.12 m

kb is constant for a given solvent. for water it is 0.512

$\bigtriangleup t_{b} = 3 \times 0.512 \times 1.12$

$\bigtriangleup t_{b} = 1.7$

the boiling point of water increases by 1.7 °c

step 3: find freezing point depression.

when a non volatile solute is added to water, it results in decrease in freezing point.

the formula to find freezing point depression is

$\bigtriangleup t_{f} = i \times k_{f} \times m$

kf is constant for water and its value is 1.86

$\bigtriangleup t_{f} = 3 \times 1.86 \times 1.12$

$\bigtriangleup t_{f} = 6.2$

the freezing point of water decreases by 6.2 °c

therefore we can say that, the solution will have a higher boiling point and a lower freezing point

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4. A 300 mL sample of a gas at a temperature of 400 K exerts a pressure of exactly one atmosphere....