A substance has a molecular formula of C8H10N4O2

The empirical formula of a substance = C₄H₅N₂O

The empirical formula is the smallest comparison of atoms of compound forming elements.  

A molecular formula is a formula that shows the number of atomic elements that make up a compound.  

(empirical formula) n = molecular formula  

((empirical formula)n=C₈H₁₀N₄O₂

divide by 2 :

(C₄H₅N₂O)₂=C₈H₁₀N₄O₂

since the atomic number is the number of protons in the nucleus, as we move to the left on the periodic table, the electrostatic pull between the nucleus and the valence electron shell decreases. as we move down a group (vertical column), the valence shell energy level gets further and further from the nucleus.

answer : third trial had the contaminated sample and the correct value for dhrxn should be 1000 kj/mol

explanation :

let us write down the given equations

equation 1 :

equation 2 :

equation 3 :

let us use hess's law to find out which 2 equations can be added to get the third equation.

let us reverse equation 2 and multiply it by 2. the new equation that we get is,

equation 4 :

let us add equation 1 & 4

the above equation is similar to equation 3 but has different value for dhrxn.

therefore third trial had the contaminated sample and the correct value for dhrxn should be 1000 kj/mol