Orbital practice

I need help on where to put these arrows at

According to the diagram; a) identify the anode of the cell and write the half-reaction that occurs there b) write the overall equation for the reaction that occurs as the cell operates c) calculate the value of the standard cell potential ,e cell. d)write the shorthand notation of the cell above e)indicate the flow of the electrons on the diagram

Why do cells appear different in distilled water than they do in 10% salt water?

Which aqueous solution of ki freezes at the lowest temperature? 1) 1 mol of ki in 500. g of water 2) 2 mol of ki in 500. g of water 3) 1 mol of ki in 1000. g of water 4) 2 mol of ki in 1000. g of water