Calculate the pH of a solution containing a caffeine concentration of 455 mg/L . Express your answer to one decimal place.

Explanation:

Caffeine is a weak base with pKb = 10.4

Kb = 10⁻¹⁰°⁴ = 3.98 x 10⁻¹¹

molecular weight of caffeine = 194.2

455 x 10⁻³ g / L = 455 x 10⁻³ / 194.2 moles / L

concentration of given solution a = 2.343 x 10⁻³ M

Let the caffeine be represented by B .

B    +   H₂O =  BH + OH⁻

a - x                   x        x  

x² / ( a - x ) = Kb

x² / ( a - x ) = 3.98 x 10⁻¹¹

x is far less than a so a -x is almost equal to a

x² = 3.98 x 10⁻¹¹ x 2.343 x 10⁻³ = 9.32  x 10⁻¹⁴

x = 3.05 x 10⁻⁷

[ OH⁻ ] = 3.05 x 10⁻⁷

pOH = - log ( 3.05 x 10⁻⁷ )

= 7 - log 3.05

= 7 - 0.484 = 6.5

pH = 14 - 6.5 = 7.5  

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